New concepts emerge for generating clean, inexpensive fuel from water

An inexpensive method for generating clean fuel is the modern-day equivalent of the philosopher’s stone. One compelling idea is to use solar energy to split water into its constituent hydrogen and oxygen and then harvest the hydrogen for use as fuel. But splitting water efficiently turns out to be not so easy. - Read more here

Splitting water into hydrogen provides a means of harvesting the hydrogen for fuel. This image depicts the water-splitting process in a light-sensitive electrode material (BiVO4), which UChicago and University of Wisconsin researchers investigated in an experimental and computational study.

Illustration by Peter Allen, Credit: University of Chicago

 

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Molecular footballs could revolutionize your next World Cup experience

A new way to assemble individual molecules could revolutionize the creation of novel materials with numerous potential applications, including emerging technologies such as flexible TVs. The results of this ground-breaking research are published on 22 June in the prestigious journal Nature Chemistry.

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Evolution of a bimetallic nanocatalyst

Atomic-scale snapshots of a bimetallic nanoparticle catalyst in action have provided insights that could help improve the industrial process by which fuels and chemicals are synthesized from natural gas, coal or plant biomass. A multi-national lab collaboration led by researchers with the U.S. Department of Energy (DOE)’s Lawrence Berkeley National Laboratory (Berkeley Lab) has taken the most detailed look ever at the evolution of platinum/cobalt bimetallic nanoparticles during reactions in oxygen and hydrogen gases. 

 

TEM image of platinum/cobalt bimetallic nanoparticle catalyst in action shows that during the oxidation reaction, cobalt atoms migrate to the surface of the particle, forming a cobalt oxide epitaxial film, like water on oil.

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New fluorescent hybrid material changes color according to direction of light

The UPV/EHU's Molecular Spectroscopy Group, in collaboration with the Institute of Catalysis and Petroleum Chemistry of the CSIC (Spanish National Research Council), has developed a highly fluorescent hybrid material that changes colour depending on the polarisation of the light that it is illuminated by. 

The research has been published in ACS Photonics, the new journal devoted exclusively to Photonics published by the American Chemical Society.

The aim with respect to hybrid materials with one organic component and another inorganic one is to combine the best attributes of each one into a single system. 

Labs across the world are working to develop new hybrid materials for technological applications in nanotechnologies, in particular, and these materials are already being used in lightweight materials for cars, sports equipment, in biomimetic materials, like prostheses, etc.

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Left: CIE system or chromaticity diagram to characterise the colours.
Above right: green emission obtained using linearly polarised light along the channels. Below right: blue emission obtained using light linearly perpendicular to the channels. NB: the arrows indicate the direction in the polarisation of the light used.

Steering Chemical Reactions with Laser Pulses

Usually, chemical reactions just take their course, much like a ball rolling downhill. 

However, it is also possible to deliberately control chemical reactions: at the Vienna University of Technology, molecules are hit with femtosecond laser pulses, changing the distribution of electrons in the molecule.  

This interaction is so short that at first it does not have any discernable influence on the atomic nuclei, which have much more mass than the electrons. However, the disturbance of the electron distribution can still initiate chemical processes and eventually separate the nuclei from each other. 

The properties of the laser pulse determine which chemical final products are created.

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Short laser pulses interacting with ethylene

 

PNNL: News - Halving hydrogen

PNNL: News - Halving hydrogen

Like a hungry diner ripping open a dinner roll, a fuel cell catalyst that converts hydrogen into electricity must tear open a hydrogen molecule.

Now researchers have captured a view of such a catalyst holding onto the two halves of its hydrogen feast. The view confirms previous hypotheses and provides insight into how to make the catalyst work better for alternative energy uses.

This study is the first time scientists have shown precisely where the hydrogen halves end up in the structure of a molecular catalyst that breaks down hydrogen, the team reported online April 22 in Angewandte Chemie International Edition. 

The design of this catalyst was inspired by the innards of a natural protein called a hydrogenase enzyme.

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Neutron crystallography shows this iron catalyst gripping two hydrogen atoms (red spheres). This arrangement allows an unusual dihydrogen bond to form between the hydrogen atoms (red dots).