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Saturday, 4 May 2013

Colligative Properties

Physical properties can be divided into two categories. Extensive properties (such as mass and volume) depend on the size of the sample. Intensive properties (such as density and concentration) are characteristic properties of the substance; they do not depend on the size of the sample being studied. 

This section introduces a third category that is a subset of the intensive properties of a system. This third category, known as colligative properties, can only be applied to solutions. By definition, one of the properties of a solution is a colligative property if it depends only on the ratio of the number of particles of solute and solvent in the solution, not the identity of the solute. 

Very few of the physical properties of a solution are colligative properties. As an example of this limited set of physical properties, let's consider what happens to the vapor pressure of the solvent when we add a solute to form a solution. We'll define Po as the vapor pressure of the pure liquid -- the solvent -- and P as the vapor pressure of the solvent after a solute has been added. 

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Credit: http://chemed.chem.purdue.edu

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